曹劍瑜

教授曹劍瑜
Email:  jycao@cczu.edu.cn; jyucao@hotmail.com

教育經(jīng)歷:

2006/09 – 2009/07, 中科院上海微系統(tǒng)與信息技術(shù)研究所, 材料物理與化學(xué), 博士

2001/09 – 2004/07, 南京師范大學(xué)化學(xué)與環(huán)境科學(xué)學(xué)院, 物理化學(xué), 碩士

工作經(jīng)歷：

2009/07 – 至今, 常州大學(xué)石油化工學(xué)院, 講師(2006) 副教授(2011) 教授(2017) 博士生導(dǎo)師(2018)

2019/01 – 2019/12, 澳大利亞昆士蘭大學(xué)生物工程與納米技術(shù)研究所, 訪問學(xué)者

2013/08 – 2014/08, 美國特拉華(Delaware)大學(xué)化學(xué)工程與分子工程系, 訪問學(xué)者

榮譽(yù)與獲獎：

江蘇省高校“青藍(lán)工程”中青年學(xué)術(shù)帶頭人(2019)

常州市自然科學(xué)論文三等獎(2019)

國家公派出國留學(xué)基金(2018)

常州市自然科學(xué)論文三等獎(2015)

江蘇省高校“青藍(lán)工程”中青年骨干教師(2014)

江蘇省教育廳公派留學(xué)基金(2013)

常州市自然科學(xué)論文二等獎(2011)

江蘇省企業(yè)博士人才項(xiàng)目(2011)

中國石油和化學(xué)工業(yè)協(xié)會(CPCIA)科技進(jìn)步獎三等獎(2010)

常州市“831高層次創(chuàng)新創(chuàng)業(yè)人才培養(yǎng)工程”首批中青年骨干人才(2009)

中國科學(xué)院所長獎(2009)

社會兼職（社會兼職填是否擔(dān)任過專業(yè)雜志編委、專業(yè)委員會委員、專業(yè)協(xié)會會員等）

中國化學(xué)會會員、國家基金委函評專家。

研究方向:

有機(jī)液流電池、新型二次電池、納米電催化

科研項(xiàng)目:

[1]國家自然科學(xué)基金面上項(xiàng)目(21975033): 基于氧化還原活性共價有機(jī)框架聚合物的水系全有機(jī)二次電池設(shè)計(jì)(2020-2023), 66萬, 主持, 在研.

[2]國家自然科學(xué)基金面上項(xiàng)目(21573025): 基于醌類衍生物電化學(xué)的全有機(jī)水系液流電池高電位電解質(zhì)研究(2016-2019), 66萬, 主持, 結(jié)題.

[3]國家自然科學(xué)基金青年基金項(xiàng)目(21103014):直接甲醇燃料電池石墨烯基擴(kuò)散層電極及傳質(zhì)機(jī)理研究(2012-2014), 主持, 結(jié)題.

[4]江蘇省自然科學(xué)基金項(xiàng)目(BK2012591):石墨烯負(fù)載金屬氫氧化物/石墨烯不對稱電化學(xué)電容器研究(2013-2014), 主持, 結(jié)題.

[5]江蘇省企業(yè)博士集聚計(jì)劃項(xiàng)目(2011Z0062)：直接甲醇燃料電池膜電極的有序結(jié)構(gòu)設(shè)計(jì)與性能研究(2011-2013), 主持, 結(jié)題.

[6]江蘇省太陽能電池材料與技術(shù)重點(diǎn)實(shí)驗(yàn)室開放課題(201106): 有序碳基復(fù)合儲能材料的制備及其電極動力學(xué)機(jī)理研究(2012-2013), 主持, 結(jié)題.

研究論文(2017-2023)

1. Yanjun Shi*, Pengcheng Wang, Haiguang Gao, Wei Jin, Yanli Chen, Yucheng Huang, Tai-Rui Wu, De-Yin Wu, Juan Xu, Jianyu Cao(曹劍瑜)*, π-Conjugated N-heterocyclic compound with redox-active quinone and pyrazine moieties as a high-capacity organic cathode for aqueous zinc-ion batteries, Chem. Eng. J., 2023, 461, 141850.

2. Xue Xia,? Mengna Qin,? Yang Sun, Yanjun Shi, Juan Xu,* Yong-Miao Shen,* Dengfeng Guo, Zhidong Chen, Jianyu Cao(曹劍瑜)*, A high-capacity 1,2:3,4-dibenzophenazine anode integrated into carbon felt for an aqueous organic flow battery in alkaline media, Green Chem., 2022, 24, 8783-8790.

3. Caixing Wang,? Yanrong Wang,? Meng Tao,? Bo Yu, Kaiqiang Zhang, Jie Wei, Yuzhu Liu, Pengbo Zhang, Guochun Ding, Zuoxiu Tie*, Jianyu Cao(曹劍瑜)*, Zhong Jin*, Highly water-soluble 6-quinoxalinecarboxylic acid for high-voltage aqueous organic redox flow batteries, ACS Appl. Energy Mater., 2022, 5, 10379-10384.

4. Chuan-Wei Feng, Dan-Yan Wang, Hui-Ling Lu, Zi-Wei Xi, Yong-Miao Shen*, Jianyu Cao(曹劍瑜)*, Photocatalytic synthesis of sulfinamides and sulfoxides from nitroarenes and thiophenols, Org. Lett., 2022, 24, 4485-4489.

5. Wenfei Zhang, Yanli Chen*, Tai-Rui Wu, Xue Xia, Juan Xu, Zhidong Chen, Jianyu Cao(曹劍瑜)*, De-Yin Wu, Computational design of phenazine derivative molecules as redox-active electrolyte materials in alkaline aqueous organic flow batteries, New J. Chem., 2022, 46, 11662-11668.

6. Hongchao Zhang,? Qinghong Huang,? Xue Xia, Yanjun Shi, Yong-Miao Shen, Juan Xu,* Zhidong Chen and Jianyu Cao(曹劍瑜)*, Aqueous organic redox-targeting flow battery based on Nernstian-potential-driven anodic redoxtargeting reactions, J. Mater. Chem. A, 2022, 10, 6740-6747.

7. Zirui Liu,? Zheng Wang,? Yanjun Shi, Yong-Miao Shen, Wenchang Wang, Zhidong Chen, Juan Xu* and Jianyu Cao(曹劍瑜)*, A high-capacity hexaazatrinaphthylene anode for aqueous organic hybrid flow batteries, J. Mater. Chem. A, 2021, 9, 27028-27033.

8. Jun Qiao, Zirui Liu, Zheng Wang, Meng Qin, Yanjun Shi, Juan Xu,* Zhidong Chen, and Jianyu Cao(曹劍瑜)*, Long-life aqueous H⁺/K⁺ dual-cation batteries based on dipyridophenazine//hexacyanoferrate electrodes, ACS Appl. Energy Mater. 2021, 4, 4903-4909.

9. Jun Qiao, Meng Qin, Yong-Miao Shen, Jianyu Cao(曹劍瑜),* Zhidong Chen and Juan Xu*, A rechargeable aqueous proton battery based on a dipyridophenazine anode and an indium hexacyanoferrate cathode, Chem. Commun., 2021, 57, 4307-4310.

10. Jianyu Cao(曹劍瑜), Junya Tian, Juan Xu* and Yonggang Wang*, Organic flow batteries: recent progress and perspectives, Energy & Fuels 2020, 34, 11, 13384-13411.

11. Wenbo Zhou, Wenjie Liu, Meng Qin, Zhidong Chen, Juan Xu*, Jianyu Cao(曹劍瑜)* and Jun Li*, Fundamental properties of TEMPO-based catholytes for aqueous redox flow batteries: effects of substituent groups and electrolytes on electrochemical properties, solubilities and battery performance, RSC Adv., 2020, 10, 21839-21844.

12. Yang Zhang, Jianyu Cao(曹劍瑜)*, Zhidong Chen*, Juan Xu* and Chengzhong Yu, An organic-based aqueous hybrid flow battery with high power and long cycle life: tetrapyridophenazine/ferrocyanide system, J. Mater. Chem. A, 2020, 8, 6874-6881.

13.Binbin Wang, Yang Zhang, Ye Zhu, Yong-Miao Shen, Wenchang Wang, Zhidong Chen*, Jianyu Cao(曹劍瑜)*, Juan Xu*, Redox-active poly (6-(1H-pyrrol-1-yl) quinoxaline) as a novel organic anode material for aqueous hybrid flow batteries, J. Power Sources, 2020, 451, 227788.

14.Yang Zhang, Wenjie Liu, Zheng Wang, Yong-Miao Shen, Wenchang Wang, Zhidong Chen, Juan Xu*, Jianyu Cao(曹劍瑜)*, Tetrapyridophenazine/graphene composites for aqueous hybrid flow battery anodes with long cycle life, Carbon, 2020, 161, 309-315.

15. Xiaolin Li, Yongsheng Zhou, Yingying Du, Juan Xu*, Wenchang Wang, Zhidong Chen*, Jianyu Cao(曹劍瑜)*, PtCu nanoframes as ultra-high performance electrocatalysts for methanol oxidation, Int. J. Hydrogen Energy, 2019, 44, 18050-18057.

16. Jianyu Cao(曹劍瑜), Fanfan Ding, Hongping Chen, Hongning Wang, Wenchang Wang, Zhidong Chen*, Juan Xu*, A new redox-active conjugated polymer containing anthraquinone pendants as anode material for aqueous all-organic hybrid-flow battery, J. Power Sources, 2019, 423, 316-322.

17. Juan Xu, Huada Cao, Chaoying Ni, Yan Wang, Jianyu Cao(曹劍瑜)*, Zhidong Chen*, Design and synthesis of sandwich-like CoNi₂S₄@C@NiCo-LDH microspheres for supercapacitors, J. Solid State Electrochem., 2019, 23, 1513-1522.

18.Juan Xu, Yonghong Yang, Yan Wang, Jianyu Cao(曹劍瑜)*, Zhidong Chen*, Enhanced electrochemical properties of manganese-based metal organic framework materials for supercapacitors, J. Appl. Electrochem., 2019, 1-12.

19. Mingming Dong, Hongping Chen, Juan Xu*, Zhidong Chen* and Jianyu Cao(曹劍瑜)*, Synthesis of Cu-decorated PtTe nanotubes with high electrocatalytic activity for oxygen reduction, J. Alloy. Compd., 2019, 770, 76-81.

20. Jianyu Cao(曹劍瑜), Meng Tao, Hongping Chen, Juan Xu*, Zhidong Chen*, A highly reversible anthraquinone-based anolyte for alkaline aqueous redox flow batteries, J. Power Sources, 2018, 386, 40-46.

21. Jianyu Cao(曹劍瑜), Yingying Du, Mingming Dong, Zhidong Chen*, Juan Xu*, Template-free synthesis of chain-like PtCu nanowires and their superior performance for oxygen reduction and methanol oxidation reaction, J. Alloy. Compd., 2018, 747, 124-130.

22. Jianyu Cao(曹劍瑜), Xiaodi Jia, Mengwei Guo, Yingying Du, Juan Xu* and Zhidong Chen*, Fe–N co-decorated hierarchically porous graphene as a highly efficient electrocatalyst for the oxygen reduction reaction, Sustain. Energ. Fuels, 2017, 2, 169-174.

23. Jianyu Cao(曹劍瑜), Zhentao Zhu, Juan Xu*, Meng Tao and Zhidong Chen*, Nitrogen-doped porous graphene as a highly efficient cathodic electrocatalyst for aqueous organic redox flow battery application, J. Mater. Chem. A, 2017, 5, 7944–7951.

24. Jianyu Cao(曹劍瑜), Yue Hu, Lijuan Chen, Juan Xu*, Zhidong Chen*, Nitrogen-doped carbon quantum dot/graphene hybrid nanocomposite as an efficient catalyst support for the oxygen reduction reaction, Int. J. Hydrogen Energy, 2017, 42, 2931-2942.

25. Juan Xu, Chaojie Ma, Jianyu Cao(曹劍瑜)* and Zhidong Chen*, Facile synthesis of core–shell nanostructured hollow carbon nanospheres@nickel cobalt double hydroxides as high-performance electrode materials for supercapacitors, Dalton Transactions, 2017, 46, 3276–3283.

26. Juan Xu, Kexing Hou, Zhengwei Ju, Chaojie Ma, Wenchang Wang, Cheng Wang, Jianyu Cao(曹劍瑜)* and Zhidong Chen*, Synthesis and Electrochemical Properties of Carbon Dots/Manganese Dioxide (CQDs/MnO₂) Nanoflowers for Supercapacitor Applications, J. Electrochem. Soc., 2017, 164(2), A430-A437.

授權(quán)專利

[1]一種鋰離子電池負(fù)極材料及其制備方法(授權(quán)), 中國發(fā)明專利,CN201310147107.4(2014)

[2]一種磷酸鐵鋰-碳-二氧化硅復(fù)合材料及其制備方法(授權(quán)), 中國發(fā)明專利,201210382917.3(2014)

[3]一種碳載Co核-Pt殼納米粒子催化劑及其制備方法(授權(quán)),中國發(fā)明專利,CN 201310524211.0(2015)(已轉(zhuǎn)讓)

[4]基于吡嗪多羧酸配體構(gòu)筑金屬錳有機(jī)框架化合物的方法及應(yīng)用(授權(quán)), 中國發(fā)明專利,201811090629.4(2021)

[5]混合液流電池陰極用TEMPO基聚吡咯及制備方法(授權(quán)), 中國發(fā)明專利, 202010064852.2 (2021) (已轉(zhuǎn)讓)

[6]單晶硅太陽能電池表面處理用制絨劑及使用方法(授權(quán)), 中國發(fā)明專利,201110177294.1 (2014)

[7]高導(dǎo)電性柔性石墨烯膜電極的制備方法(授權(quán)), 中國發(fā)明專利,201310243138.X (2015)

[8]一種超級電容器用鎳鈷雙氫氧化物/含氮碳納米角復(fù)合材料及其制備方法(授權(quán)), 中國發(fā)明專利,201610414633.6(2018)

[9]一種有機(jī)電解液體系不對稱電化學(xué)電容器及其制備方法(授權(quán)), 中國發(fā)明專利,201310350232.5(2015) (轉(zhuǎn)讓)

[10]一種含氮碳量子點(diǎn)/石墨相氮化碳復(fù)合光催化劑的制備方法(授權(quán)), 中國發(fā)明專利,201710497252.3(2019)

[11]一種基于金屬有機(jī)配合物液流正極的水系單液流電池及其制備方法(授權(quán)), 中國發(fā)明專利,201710578191.3(2019)

[12]一種以碳納米角/聚酰亞胺復(fù)合物為固體負(fù)極的鄰菲羅啉鐵配合物-水系半液流電池(授權(quán)), 中國發(fā)明專利,201811157300.5 (2021)(獨(dú)占許可)

[13]基于含氧化還原活性側(cè)基單元的共軛微孔聚合物負(fù)極的水系全有機(jī)混合液流電池(授權(quán)), 中國發(fā)明專利,202011355637.4 (2021)(獨(dú)占許可)

[14]基于電活性吩嗪衍生物負(fù)極的堿性水系混合液流電池(授權(quán)), 中國發(fā)明專利,202011380434.0 (2021)(獨(dú)占許可)

[15]一種COF負(fù)載的金屬氫氧化物電極的制備方法及其應(yīng)用(授權(quán)), 中國發(fā)明專利,201910619326.5 (2021)

[16]一種基于吡啶基吩嗪的高功率長壽命的中性水系混合液流電池(授權(quán)), 中國發(fā)明專利, 201911195708.6 (2022)(獨(dú)占許可)

[17]一種基于聚吡咯喹喔啉負(fù)極的全水系混合液流電池及制備方法(授權(quán)), 中國發(fā)明專利, 201911073961.4 (2022)(獨(dú)占許可)

[18]基于具有多種氧化態(tài)嗪類化合物的水系全有機(jī)二次電池(授權(quán)), 中國發(fā)明專利, 202110589675.4 (2022)