黃海 教授
E-mail: huanghai@cczu.edu.cn
課題組網頁：https://www.x-mol.com/groups/huanghaicczu
教育經歷
2016.02-2017.01 美國內華達大學拉斯維加斯分校，博士聯(lián)合培養(yǎng)，導師: Prof. Jun Yong Kang
2011.09-2016.12 南京工業(yè)大學，博士學位，導師: 朱紅軍 教授
2007.09-2011.07 南京工業(yè)大學，學士學位
工作經歷
2020.01-至今 常州大學，教授
2019.05-2019.12 常州大學，一類雇員（香港科技大學博士后身份）
2018.07-2019.12 香港科技大學，博士后，合作導師: Prof. Jianwei Sun
2017.02-2018.04 美國內華達大學拉斯維加斯分校，博士后，合作導師: Prof. Jun Yong Kang.
承擔項目
國家自然科學基金青年基金（22201023），30萬，2023-2025
企業(yè)技術開發(fā)項目，60萬，2022-2024
江蘇省中以產業(yè)技術研究院開放課題（JSIITRI202205），3萬，2022
江蘇省雙創(chuàng)人才（JSSCRC2021536），50萬，2021-2024.
江蘇省自然科學青年基金（BK20210849），20萬，2021-2024.
國家自然基金重大研究計劃-培育項目（91956114），37.5萬，2020-2022.
江蘇省高等學校自然科學研究面上項目（20KJB150012），5萬，2020-2022.
常州市應用基礎研究計劃（CJ20200082），5萬，2020-2022.
國家博士后基金-B類資助（2018M642226），5萬，2018-2019.
江蘇省博士后基金-A類資助（2018K027A），8萬，2018-2019.
獲獎情況
2020年度 ACS 個人貢獻獎
2020年度 常州市十大青年科技新銳
2021年度 常州市第十六次自然科學優(yōu)秀論文一等獎
科研方向
有機合成方法學：炔烴導向性官能團化，不對稱催化，光催化等
論文發(fā)表
2022年
34. Hongling Xie, Zhenkun Yang, Luning Tang, Zhengyu Han,* Jianwei Sun,* and Hai Huang.* Construction of Nine-memberedN,N,O-Heterocycles via Pdcatalyzed [6+3] Dipolar Cycloaddition.Chem. Commun.,2022,58, 10560-10563.
30. Danfeng Wang, Hai Huang*, Xiaolin Zhu*. Development of Anthrazoline Photocatalyst for Promoting Amination and Amidation Reactions. Chem. Commun. 2022, 58, 3529-3532.
29. Tianyu Zhang, Han Zhuang, Luning Tang, Zhengyu Han, Wengang Guo, Hai Huang,* and Jianwei Sun*. Catalytic Enantioselective Synthesis of 2,3-Dihydrobenzo[b]oxepines via Asymmetric Oxetane Opening by Internal Carbon Nucleophiles. Org. Lett.2022, 24, 207-212.
2021年
27. Tianyu Zhang, Zhenkun Yang, Dapeng Zhou, Fuliang Meng, Zhengyu Han*, Hai Huang*.Non-metal Lewis acid-catalyzed cross-Claisen condensation for β-keto esters. Org. Biomol. Chem. 2021, 19, 9163-9166.
26. Shuxuan Liu, Hui Qian, Tianyu Zhang, Hongling Xie, Zhengyu Han, Wengang Guo, Hai Huang,* and Jianwei Sun*.Mild Intermolecular Synthesis of a Cyclopropane-Containing Tricyclic Skeleton: Unusual Reactivity of Isobenzopyryliums. Angew. Chem. Int. Ed.2021, 60, 21272-21276.
25. Wengang Guo, Min Wang, Zhengyu Han, Hai Huang* and Jianwei Sun*. Organocatalytic asymmetric synthesis of a-amino esters from sulfoxonium ylides. Chem. Sci., 2021, 12, 11191-11196.
24. Song Sun, Zhaobin Wang, Shijia Li, Cong Zhou, Lijuan Song, Hai Huang,* and Jianwei Sun*. An Organocatalytic Kinetic Resolution of Aziridines by Thiol Nucleophiles. Org. Lett.2021, 23, 554-558.
23. Hai Huang, Tianyu Zhang, and Jianwei Sun*. Mild C–C Bond Formation via Lewis Acid Catalyzed Oxetane Ring Opening with Soft Carbon Nucleophiles. Angew. Chem. Int. Ed. 2021, 60, 2668-2673.Highlighted by CBG.
22. Shuxuan Liu, Yu Zang, Hai Huang*, and Jianwei Sun*. In(OTf)3-Catalyzed Synthesis of 2,3-Dihydro-1H-benzo[e]indoles and 2,3-Dihydrobenzofurans via [3 + 2] Annulation. Org. Lett. 2020, 22, 8219-8223.
21. Guannan Wang#, Hai Huang#, Wengang Guo, Chenxiao Qian, Jianwei Sun,*Unusual Skeletal Reorganization of Oxetanes for the Synthesis of 1,2-Dihydroquinolines.Angew. Chem. Int. Ed. 2020, 59,11245-11249.(# Co-first author)Highlighted by Synfacts.
2019年
20. Hai Huang, Wen Yang, Zuliang Chen, Zengwei Lai, Jianwei Sun,* A mild catalytic synthesis of 2-oxazolines via oxetane ring-opening: rapid access to a diverse family of natural products. Chem. Sci., 2019, 10, 9586-9590.
入職常州大學前
19. Hai Huang, Johanna Denne, Chou-Hsun Yang, Haobin Wang, Jun Yong Kang.* Direct Aryloxylation/Alkyloxylation of Dialkyl Phosphonates for the Synthesis of Mixed Phosphonates [J]. Angew. Chem. Int. Ed. 2018, 57, 6624-6628. (Highlighted by UNLV news; Highlighted by Synpacts)
18. Hai Huang, Jun Yong Kang.* New Strategies for Activation of Phosphonates/Phosphates toForge Functional Phosphorus Compounds [J]. Synlett, 2019, 30, 635-641.
17. Hai Huang, Jeffrey Ash, Jun Yong Kang.* Tf2O Promoted Activating Strategy of Phosphate Analogues: Synthesis of Mixed Phosphates and Phosphinate [J]. Org. Lett.2018, 20, 4938-4941. (Highlighted by Organic Chemistry Portal).
16. Hai Huang, Jeffrey Ash, Jun Yong Kang.*Base-Controlled Fe(Pc)-Catalyzed Aerobic Oxidation of Thiols for the Synthesis of S-S and S-P(O) Bond [J]. Org. Biomol. Chem.2018, 16, 4236-4242.
15. Hai Huang, Hongjun Zhu, Jun Yong Kang.* Regio- and Stereoselective Hydrophosphorylation of Ynamides for the Synthesis of β-Aminovinylphosphine Oxides [J]. Org. Lett.2018, 20, 2778-2781.
14. Manasa Shetty,# Hai Huang,# Jun Yong Kang.* Regioselective Synthesis of α- and γ-Amino Quinolinyl Phosphonamides using N-Heterocyclic Phosphines (NHPs) [J]. Org. Lett.2018, 20, 700-703. (# Co-first author)
13. Hai Huang, Jun Yong Kang.* Organocatalytic Phosphonylation of in Situ Formed o Quinone Methides [J]. Org. Lett. 2017, 19, 5988-5991.
12. Hai Huang, Jun Yong Kang.* Oxidation-Reduction Condensation of Diazaphosphites for Carbon-Heteroatom Bond Formation Based on Mitsunobu Mechanism [J]. Org. Lett. 2017, 19, 544-547.
11. Luning Tang,# Hai Huang,# Yang Xi, Guangke He, Hongjun Zhu.* Pd/Cu-Catalyzed Tandem Head-to-tail Dimerization/Cycloisomerization of Terminal Ynamides for the Synthesis of 5-Vinyloxazolones [J]. Org. Biomol. Chem.2017, 15, 2923-2930 (# Co-first author)
10. Hai Huang, Jun Yong Kang.* Mitsunobu Reaction Using Basic Amines as Pronucleophiles [J]. J. Org. Chem. 2017, 82, 6604-6614. (Most Read Articles in JOC, 2017; Highlighted in Synfacts, 2017, 13, 807)
9. Hai Huang, Jake Palmas, Jun Yong Kang.* A Reagent-Controlled Phospha Michael Addition Reaction of Nitroalkenes with Bifunctional N-Heterocyclic Phosphine (NHP) Thioureas [J]. J. Org. Chem. 2016, 81, 11932-11939.
8. Hai Huang, Luning Tang, Xiaobo Han, Guangke He, Yang Xi, Hongjun Zhu.* Regioselective Iodoamination of Terminal Ynamides for the Synthesis of α-amino-β,β-diiodo-enamides [J]. Chem. Commun., 2016, 52, 4321-4324.
7. Hai Huang, Luning Tang, Qi Liu, Yang Xi, Guangke He,* Hongjun Zhu.* Formation of α-Chalcogenyl Acrylamides through Unprecedented Chalcogen Mediated Metal-Free Oxyfunctionalization of Ynamides with DMSO as Oxidant. Chem. Commun., 2016, 52, 5605-5608.
6. Hai Huang, Jun Yong Kang.* Amine-Catalyzed Phospha-Michael Reaction of α, β-Unsaturated Aldehydes and Ketones with Multifunctional N-Heterocyclic Phosphine-Thioureas as Phosphonylation Reagent. Org. Lett., 2016, 18, 4372-4375.
5. Hai Huang, Junzhen Fan, Guangke He,* Zhimin Yang, Xiaodong Jin, Qi Liu, Hongjun Zhu.* Generation of Oxazolidine-2,4-diones Bearing Thio-Quaternary Carbons by Oxothiolation / Cyclization of Ynamides. Chem. Eur. J., 2016, 22, 2532-2538.
4. Hai Huang, Luning Tang, Yang Xi, Guangke He, Hongjun Zhu.* Metal-free Hydration of Ynamides: Convenient Approach to Amides. Tetrahedron Lett.,2016, 57, 1873-1876.
3. Hai Huang, Guangke He, Guohao Zhu, Xiaolin Zhu, Shineng Qiu, Hongjun Zhu.* Palladium-Catalyzed Intramolecular Cyclization of Ynamides: Synthesis of 4-Halo-oxazolones. J. Org. Chem., 2015, 80, 3480-3487.
2. Hai Huang, Xiaolin Zhu, Guangke He, Qi Liu, Junzhen Fan, Hongjun Zhu.* Controlled Synthesis of 1,3,5-Oxadiazin-2-ones and Oxazolones through Regioselective Iodocyclization of Ynamides. Org. Lett., 2015, 17, 2510-2513.
1. Hai Huang, Guangke He, Xiaolin Zhu, Xiaodong Jin, Shineng Qiu, Hongjun Zhu.* Iodine-Mediated Oxidation of Ynamides: A Facile Access to N-Monosubstituted α-Ketoamides and α-Ketoimides. Eur. J. Org. Chem., 2014, 7174-7183.
