碩士生導師、教授名單

陳銘

發(fā)布時間：2021-08-25瀏覽次數(shù)：4691

教授：陳銘

Email :chenming0228@cczu.edu.cn

個人主頁：https://www.x-mol.com/groups/chenming


教育經(jīng)歷:

  • 2006/09-2010/06，蘇州大學 材料與化學化工學部，學士學位.

  • 2010/09-2015/06，中國科學院上海有機化學研究所，博士學位. 導師：劉元紅 研究員


工作經(jīng)歷：

  • 2015/07-2016/06，中國科學院上海有機化學研究所, 劉元紅研究員課題組 研究助理.

  • 2016/08-2020/11, 美國芝加哥大學，博士后，導師： Prof. Guangbin Dong.

  • 2021/03-至今，常州大學，教授


個人榮譽：

  1. 2021年，入選江蘇省特聘教授

  2. 2015 年，劉鑄晉優(yōu)秀博士生獎學金；

  3. 2015 年，中國科學院大學優(yōu)秀畢業(yè)生；

  4. 2015 年，北京市普通高等學校優(yōu)秀畢業(yè)生；

  5. 2014 年，中國科學院大學三好學生；

  6. 2014 年，中國科學院大學優(yōu)秀學生干部；


研究方向:

  • 圍繞有機化學為中心，旨在解決有機合成化學中長期存在的挑戰(zhàn)性課題。

  • 主要以過渡金屬催化為手段，通過設計合成新型的催化劑、配體，發(fā)展高活性、

  • 實用的有機合成方法學，實現(xiàn)一些重要的（手性）合成砌塊的高效合成。


教學科研項目:

  • 教學：基礎(chǔ)化學實驗，研究生波譜分析（理）

  • 科研項目：國自然青年科學基金項目，領(lǐng)軍型創(chuàng)新人才引進培育項目C類



發(fā)表論文:

  • Publications in CCZU:


11. Tang, Lu-ning.; Liu, Guo-ying.; Li, Jun-hua and Chen, Ming.*Palladium-Catalyzed Diversified Synthesis of mono-Fluorinated Alkenes from Allylic gem-Difluorides through Pd-OH intermediate. Org. Lett.2023, 25, 9064-9069. DOI:10.1021/acs.orglett.3c03917.



10.  Yang, Sen.; Hu, Hao.; Li, Jun-hua and  Chen, Ming.* Direct Alkylation of Glycine Derivatives via Photoinduced Palladi-um Catalysis, Utilizing Intermolecular Hydrogen Atom Transfer Mediated by Alkyl Radicals. 

ACS Catalysis. 2023, 13, 24, 15652?15662. DOI:10.1021/acscatal.3c04075.






9. Kong, Xian-qiang.; Chen, Yi-yi.; Chen, Xiao-hui.; Ma, Cheng.; Chen, Ming.; Wang, Wei.; Xu, Yuan-Qing.; Ni, Shao-Fei.; Cao, Zhong-Yan.*  Organomediated electrochemical fluorosulfonylation of aryl triflates via selective C–O bond cleavage.

Nat. Commun. 2023, 14, 6933.

DOI: 10.1038/s41467-023-42699-0.

8. Yang, Sen.; Hu, Hao.; and  Chen, Ming.*  Photoinduced Palladium-Catalyzed Regio- and Chemoselective Elimination of Primary Alkyl Bromides: A Mild Route to Synthesize Unactivated Terminal Olefins. 

Org. Lett. 2023, 25, 7968-7973. DOI: 10.1021/acs.orglett.3c02980.





7.  Chen, Jia-ming.; Li, Jun-hua.; Xie, Li-cheng.; Fan, Hui-ke.; Sheng, Xia-xin.; Du, Yu-jia.; Liu, Guo-ying.; Hu, Hao.; Jiang, Yan*.; and Chen, Ming.* Iron-Catalyzed Divergent Approach to Naphthyridinones and Quinolinones: Leveraging Povarov and Carbonyl-Alkyne Metathesis Reactions of Electron Deficient Alkynes.

  Org. Chem. Front. 2023, 10, 5505-5511. DOI:10.1039/D3QO01302B.







6.  Li, Pei-shang.; Teng, Qiaoqiao*.; and Chen, Ming.*  Photoinduced Radical Cascade Domino Heck Coupling of N-Aryl Acrylamide with Vinyl Arenes Enabled by Palladium Catalysis. Chem. Commun. 2023, 59, 10620-10623.  DOI: 10.1039/D3CC03506A.




5. Yang, Sen.; Guo-ying, Liu.;  Fan, Huike.; Jun-hua, Li.; Teng, Qiaoqiao*.; and Chen, Ming.*  Sodium Hydroxide (NaOH)-Mediated Oxidative Hydroxylation of Arylboronic Acids and Its Applications in C-O Bond Formation. 

Eur. J. Org. Chem. 2023, e202300517. DOI: 10.1002/ejoc.202300517. 

(Dedicated to celebrate the 45th anniversary of Changzhou University)


4. Sheng, Xiaxin?.; Du, Yujia?.; Li, Junhua.; Teng, Qiaoqiao.*; and  Chen, Ming.* Photo-induced Nitrogen-to-Alkyl Radical Relay Heck Reaction of o-Alkylbenzamide with Vinyl Arenes by Palladium Catalysis. Org. Lett. 2023, 25, 3664-3669. DOI : 10.1021/acs.orglett.3c01030.





3. Du, Yujia?.; Sheng, Xiaxin?.; Li, Junhua.; Chen, Jiaming.; Yang, Sen. *; and  Chen, Ming.* Aryl-to-Alkyl Radical Relay Heck Reaction of Amides with Vinyl Arenes.  Chem.Sci. 2023, 14, 3580-3586. DOI: 10.1039/D2SC06852D.




2. Fan, Huike, Yang, Sen.; Li, Junhua.; Teng, Qiaoqiao*.; and Chen, Ming.*  BaO-Catalyzed α-Deuteration of Ketones, Sulfones, Sulfoxides, and Nitriles. Eur. J. Org. Chem. 2022, e202201218. DOI: 10.1002/ejoc.202201218.






1. Yang, Sen.; Fan, Huike.; Xie, Licheng.; Dong, Guangbin*.; and Chen, Ming.* Photoinduced Desaturation of Amides by Palladium Catalysis. Org. Lett. 2022, 24, 6460-6465.






  • Publications prior to CCZU:

1. Chen, M.; Chen, Y.; Sun, N.; Zhao, J.; Liu, Y.* Gold-Catalyzed Oxidative Ring Expansion of 2-Alkynyl-1,2-Dihydropyridines or -quinolines: Highly Efficient Synthesis of Functionalized Azepine or Benzazepine Scaffolds. Angew. Chem. Int. Ed.2015,54, 1200.

2. Chen, M.; Dong, G.* Direct Catalytic Desaturation of Lactams Enabled by Soft Enolization.J. Am. Chem. Soc.2017, 139, 7757. (Highlighted by Org. Process Res. Dev. 2017, 21, 1873.)

3. Chen, M.; Liu, F.; Dong, G.* Direct Palladium-Catalyzed β-Arylation of Lactams. Angew. Chem. Int. Ed. 2018,57, 3815.

4. Chen, M; Rago, A; Dong, G* Platinum-Catalyzed Desaturation of Lactams, Ketones and Lactones.  Angew. Chem. Int. Ed. 2018, 57, 16205. (Highlighted by Synfacts, 2019, 173)

5. Chen, M.; Dong, G.* Copper-Catalyzed Desaturation of Lactones, Lactams and Ketones under pH-Neutral Conditions.J. Am. Chem. Soc.2019, 141, 14889.

6. Chen, M.; Dong, G.* Platinum-catalyzed α,β-Desaturation of Cyclic Ketones through Direct Metal-enolate Formation. Angew. Chem. Int. Ed. 2021, 60, 7956.

7. Chen, M.; Chen, Y.; Liu, Y.* Palladium-catalyzed highly e?cient synthesis of tetracenes and Pentacenes.Chem. Commun.2012, 48, 12189.

8. Chen, M.; Liu, J.; Wang, L.; Zhou, X.; Liu, Y.* Gold-catalyzed cascade cycloisomerization of 1,7-diyn-3,6-bis(propargyl carbonate)s: stereoselective synthesis of naphtho[b]cyclobutenes. Chem. Commun.2013, 49, 8650.(Highlighted by Synfacts, 2014, 144)

9. Chen, M.; Sun, N.; Liu, Y.*Environmentally Benign Synthesis of Indeno[1,2-b]quinolines via an Intramolecular Povarov Reaction.Org.Lett.2013, 15, 5574.

10. Chen, M.; Sun, N.; Xu, W.; Zhao, J.; Wang, G.; Liu, Y.* Gold-Catalyzed Ring Expansion of alkynyl heterocycle via 1,2-Migration of an Endocyclic C-Heteroatom Bond. Chem. Eur. J,2015, 21, 18571.

11. Chen, M?.; Sun, N?.; Chen, H.; Liu, Y.* Dioxazoles, a new mild nitrene transfer reagent in gold catalysis: highly efficient synthesis of functionalized oxazoles. Chem. Commun.2016, 52, 6324.

12. Chen, Y.; Chen, M.; Liu, Y.* Gold-Catalyzed Cyclization of 1,6-Diyne-4-en-3-ols: Stannyl Transfer from 2-Tributylstannylfuran Through Au/Sn Transmetalation.Angew. Chem. Int. Ed.2012, 51, 6181.

13. Chen, Y.; Chen, M.; Liu, Y.* Gold-Catalyzed Cascade Cyclizations of 1,6-Diynyl Carbonates to Benzo[b]fluorenes Involving Arylation of Oxocarbenium Ion Intermediates and Decarboxylative Etherification.Angew. Chem. Int. Ed.2012, 51, 6493. (Highlighted by  Synfacts2012, 969).

14. Sun, N.; Chen, M.; Liu, Y.* Gold-Catalyzed Oxidative Reactions of Propargylic Carbonates Involving 1,2-Carbonate Migration: Stereoselective Synthesis of Functionalized Alkenes. J. Org. Chem,2014, 79, 4055.

15. Liu, J.; Chen, M.; Zhang, L.; Liu, Y.* Gold(I)-Catalyzed 1,2-Acyloxy Migration/[3+2] Cycloaddition of 1,6-Diynes with an Ynamide Propargyl Ester Moiety: Highly Efficient Synthesis of Functionalized Cyclopenta[b]indoles. Chem. Eur. J.2015, 21, 1009.

16. Li, X.; Chen, M.; Xie, X.; Sun, N.; Li, S*.; Liu, Y*. Synthesis of Multiple-Substituted Pyrroles via Gold(I)-Catalyzed Hydroamination/Cyclization Cascade. Org. Lett.2015, 17, 2984.

17. Sun, R.; Liu, J.; Yang, S.; Chen, M.; Sun, N.; Chen, H.; Xie, X.; You, X.; Li, S.; Liu, Y.* Cp2TiCl2-Catalyzed cis-Hydroalumination of Propargylic Amines with Red-Al: Stereoselective Synthesis of Z-Configured Allylic Amines. Chem. Commun.2015, 51, 6426.

18. Xu, W.; Chen, M.; Sun, N.; Liu, Y.* Gold-catalyzed cyclization of 1,6-diynyl dithioacetals via 1,7-carbene transfer and aromatic C–H functionalization.Chem. Commun.2016, 52, 11000.

19. Hu, H?.; Hu, X?.; Chen, M.; Sun, N.;* Liu, Y.* Gold-Catalyzed Ring Expansion Reaction: Highly Efficient Synthesis of Functionalized 2,3-Benzodiazepine Scaffolds.Chin. J. Org. Chem.2018, 38, 190.



授權(quán)專利：

  1.  專利：一種α-氘代酮、腈、亞砜類化合物的的制備方法.  陳銘，樊慧柯.  申請?zhí)枺?/span>202210465715.9  

  2.  專利：一種烯丙基單氟化合物的合成方法.陳銘，劉國營，唐路寧. 申請?zhí)枺?/span>202310058291.9

  3.  專利：可見光驅(qū)動非天然氨基酸及其衍生物的合成方法. 楊森; 陳銘;胡浩. 申請?zhí)枺?/span>202310791881.2

  4.  專利：抗腫瘤活性分子苯并[b]氮雜卓衍生物及其合成方法和應用. 陳銘;杜俞佳; 盛夏鑫. 申請?zhí)枺?/span>202311141245.1.

5. 專利：單氟1，4-烯炔類化合物的合成方法.陳銘，劉國營，申請?zhí)枺?/span>202311476602.X

6. 劉元紅，陳銘，陳宜峰, 并四苯及并五苯類化合物的合成方法, 中國發(fā)明專利,申請?zhí)?/span>: 201210359027. 申請日期：2012-9-24. 專利號：CN103664499A.  (導師為第一作者)





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